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Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min, Thermo Scientific Chemicals Product Code.: 11307547
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Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min, Thermo Scientific Chemicals

Product Code. 11307547
5 g
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1 g
5 g
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Product Code. 11307547

Brand: Thermo Scientific Alfa Aesar 012760.06

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Description

Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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Chemical Identifiers

CAS 51364-51-3
Molecular Formula C51H42O3Pd2
Molecular Weight (g/mol) 915.73
MDL Number MFCD00013310
InChI Key CYPYTURSJDMMMP-UHFFFAOYSA-N
Synonym tris dibenzylideneacetone dipalladium 0, tris dibenzylideneacetone dipalladium, pd2 dba 3, tris dibezylideneacetone dipalladium, tris dibenzylideneacetone dipalladium o, tris dibenzylideneacetonyl bis-palladium, tris dba, tris 1e,4e-1,5-diphenylpenta-1,4-dien-3-one dipalladiumShow MoreShow Less
PubChem CID 9811564
IUPAC Name (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
SMILES [Pd].[Pd].O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1.O=C(C=CC1=CC=CC=C1)C=CC1=CC=CC=C1Show MoreShow Less

Specifications

Melting Point 152°C to 155°C
Quantity 5 g
Sensitivity Air and moisture sensitive
Solubility Information Soluble in chlorinated solvents,benzene and THF.
Formula Weight 915.74
Physical Form Powder
Chemical Name or Material Tris(dibenzylideneacetone)dipalladium(0)

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Lot Number Certificate Type Date Catalog Number
Lot NumberN13J008 Certificate TypeCertificate of Analysis Date24/10/2023 Catalog Number012760.06,012760.03
Lot NumberR16J026 Certificate TypeCertificate of Analysis Date24/05/2023 Catalog Number012760.06,012760.03
Lot NumberM25I004 Certificate TypeCertificate of Analysis Date12/04/2022 Catalog Number012760.06,012760.03
Lot Number10238835 Certificate TypeCertificate of Analysis Date12/04/2022 Catalog Number012760.06,012760.03
Lot NumberW17H010 Certificate TypeCertificate of Analysis Date17/11/2021 Catalog Number012760.06,012760.03

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