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  7. Triisopropylsilane, 98%, Thermo Scientific Chemicals

Triisopropylsilane, 98%, Thermo Scientific Chemicals

Product Code. 11322157
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Quantity:
5 g
25 g
100 g

Description

Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 6485-79-6
Molecular Formula C9H22Si
Molecular Weight (g/mol) 158.36
MDL Number MFCD00009657
InChI Key YDJXDYKQMRNUSA-UHFFFAOYSA-N
Synonym triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855
PubChem CID 6327611
SMILES CC(C)[SiH](C(C)C)C(C)C

Specifications

Boiling Point 166°C
Quantity 100 g
Linear Formula [(CH3)2CH]3SiH
UN Number UN1993
Beilstein 1733718
Flash Point 35°C (95°F)
Solubility Information Immiscible with water.
IUPAC Name tri(propan-2-yl)silicon
Formula Weight 158.36
Percent Purity 98%
Odor Mild
Refractive Index 1.434
Density 0.773
Chemical Name or Material Triisopropylsilane
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Safety and Handling

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Product Identifier
  • Triisopropylsilane
 Signal Word
  • Warning
 Hazard Category
  • Serious eye damage/eye irritation Category 2
  • Flammable liquid Category 3
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H226-Flammable liquid and vapour.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Supplemental information
  • MIXTURE LIST-Contains : Triisopropylsilane

RUO – Research Use Only

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