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Ruthenium(III) 2,4-pentanedionate, Ru 24% min, Thermo Scientific Chemicals

For Hydrogenation

143.72 EUR - 636.17 EUR

Chemical Identifiers

CAS 14284-93-6
Molecular Formula C15H21O6Ru
Molecular Weight (g/mol) 398.40
MDL Number MFCD00000030
InChI Key RTZYCRSRNSTRGC-LNTINUHCSA-K
Synonym ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
PubChem CID 5488829
SMILES [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
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Products 2
Product Code Brand Quantity Price Quantity & Availability  
Product Code Brand Quantity Price Quantity & Availability  
11300729
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Thermo Scientific Alfa Aesar
010568.03
1 g
143.72 EUR
1g
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11310729
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Thermo Scientific Alfa Aesar
010568.06
5 g
636.17 EUR
5g
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Description

Description

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

14284-93-6
398.40
RTZYCRSRNSTRGC-LNTINUHCSA-K
5488829
C15H21O6Ru
MFCD00000030
ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
[Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

Specifications

260°C (decomposition)
White
C15H21O6Ru
ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+
RTZYCRSRNSTRGC-LNTINUHCSA-K
(Z)-4-oxopent-2-en-2-olate;ruthenium(3+)
5488829
Red crystals
14284-93-6
Crystalline
MFCD00000030
Soluble in most organic solvents such as acetone,chlorinated hydrocarbons,alcohols,cyclohexane and benzene. Insoluble in water.
[Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
398.40
398.4
Ruthenium(III) 2, 4-pentanedionate, Ru 24% min.
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Safety and Handling

Safety and Handling

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'einecsNumber' : 238-193-0

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

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Product Certifications

RUO – Research Use Only