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Rhodium(II) acetate, dimer, Premion™, 99.99% (metals basis), Rh 46.2% min, Thermo Scientific Chemicals
For Use in Cyclopropanation of Alkenes
POA - 1273.34 EUR
Chemical Identifiers
| CAS | 15956-28-2 |
|---|---|
| Molecular Formula | C8H12O8Rh2 |
| Molecular Weight (g/mol) | 441.99 |
| MDL Number | MFCD00003538 |
| InChI Key | VOXKIADTKKPBBP-UHFFFAOYSA-N |
| Synonym | rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium |
| PubChem CID | 122130469 |
| SMILES | C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4 |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11380709
|
Thermo Scientific Alfa Aesar
010560.01 |
0.25 g |
328.64 EUR
0.25g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11370709
|
Thermo Scientific Alfa Aesar
010560.03 |
1 g |
1273.34 EUR
1g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11360709
|
Thermo Scientific Alfa Aesar
010560.06 |
5 g |
POA
5g |
N/A | Please sign in to purchase this item. Need a web account? Register with us today! | ||||
Description
Catalyst for cyclopropanation of alkenes, oxidation of alcohols, cyclization reactions involving -diazo carbonyl groups, insertion into C-H and X-H bonds (X-H is NH or SH or OH) and for ylide formation. More reactive and useful in differentiating ribonucleosides and deoxynucleosides. It is also used in functionalizing fullerenes into polymers. Efficient catalyst for hydrogen transfer from 2-propanol to cyclohexanone and other unsaturated compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 15956-28-2 | |
| 441.99 | |
| VOXKIADTKKPBBP-UHFFFAOYSA-N | |
| 122130469 |
| C8H12O8Rh2 | |
| MFCD00003538 | |
| rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium | |
| C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4 |
Specifications
| 205°C | |
| Green | |
| 99.99% (metals basis) | |
| MFCD00003538 | |
| Soluble in aqueous solution like water. Slightly soluble in ethanol | |
| C[C-]1O[Rh++]234O[C-](C)O[Rh++]2(O1)(O[C-](C)O3)O[C-](C)O4 | |
| 441.99 | |
| 441.99 | |
| Green powder |
| 15956-28-2 | |
| Powder | |
| C8H12O8Rh2 | |
| rhodium ii acetate, rhodium diacetate, acetic acid, rhodium 2+ salt, rhodium ii acetate dimer dihydrate, dirhodium tetraacetate, rhodium ii acetate dimer, rhodium acetate, brown, water soluble, diacetoxyrhodium | |
| VOXKIADTKKPBBP-UHFFFAOYSA-N | |
| rhodium(2+);tetraacetate | |
| 122130469 | |
| Odorless | |
| Rhodium(II) acetate, dimer, Rh 46.2% min. |
Safety and Handling
P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
H315-H319
missing translation for 'einecsNumber' : 240-084-8
missing translation for 'rtecsNumber' : VI9361000
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
Supplemental information
- Rhodium(II) acetate, dimer
Signal Word
- Warning
Hazard Category
- Serious eye damage/eye irritation Category 2
- Skin corrosion/irritation Category 2
Hazard Statement
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
Precautionary Statement
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental information
- MIXTURE LIST-Contains : Rhodium(II) acetate
RUO – Research Use Only