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Allylmagnesium chloride, 1M in MeTHF, Thermo Scientific Chemicals

Product Code. 15478057
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Quantity:
100 mL
500 mL
This item is not returnable. View return policy
This item is not returnable. View return policy

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Solubility
It reacts violently with water.

Notes
Air & moisture sensitive. Stable under recommended storage conditions.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 2622-05-1
Molecular Formula C3H5ClMg
Molecular Weight (g/mol) 100.83
MDL Number MFCD00000473
InChI Key PLYLAFITHJUEGX-UHFFFAOYSA-M
Synonym allylmagnesium chloride, magnesium, chloro-2-propenyl, magnesium, chloro-2-propen-1-yl, chloro prop-2-en-1-yl magnesium, allylmagnesium chloride solution, 2.0 m in thf, sjpdadpprujp@, allylmagnesiumchloride, allyl magnesium chloride, allyl-magnesium chloride, 2-propenyl magnesium chloride
PubChem CID 75804
IUPAC Name magnesium;prop-1-ene;chloride
SMILES Cl[Mg]CC=C

Specifications

Linear Formula CH2=CHCH2MgCl
Quantity 100 mL
UN Number UN3399
Sensitivity Air and moisture sensitive
Solubility Information It reacts violently with water.
Formula Weight 100.83
Concentration or Composition (by Analyte or Components) 1M in MeTHF
Chemical Name or Material Allylmagnesium chloride
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Product Identifier
  • Allylmagnesium chloride, 1M in MeTHF
Signal Word
  • Danger
Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Skin corrosion/irritation Category 1 B
  • Substance which\, in contact with water\, emits flammable gases Category 1
Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H260-In contact with water releases flammable gases which may ignite spontaneously.
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • EUH014-Reacts violently with water.
  • EUH019-May form explosive peroxides.
Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P231+P232-Handle under inert gas. Protect from moisture.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
  • P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.
Supplemental information
  • MIXTURE LIST-Contains : 2-Methyltetrahydrofuran, chloro-2-propenyl-magnesium

RUO – Research Use Only

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