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  6. 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Chemical Identifiers

CAS 12150-46-8
Molecular Formula C34H28FeP2
Molecular Weight (g/mol) 554.39
MDL Number MFCD00001422
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
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Description

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
Specifications

Chemical Identifiers

12150-46-8
554.39
KZPYGQFFRCFCPP-UHFFFAOYSA-N
[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
C34H28FeP2
MFCD00001422
λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)

Specifications

12150-46-8
0.97
MFCD00001422
Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
554.39
97%
∽182°C (decomposition)
C34H28FeP2
Air sensitive
KZPYGQFFRCFCPP-UHFFFAOYSA-N
λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
554.4
1, 1'-Bis(diphenylphosphino)ferrocene
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335

P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c

H301-H312-H332

missing translation for 'dotInformation' : Hazard Class: 6.1; Packaging Group: III

missing translation for 'tsca' : No

missing translation for 'storageNote' : Air Sensitive

Recommended Storage : Keep cold; Store under Argon

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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